Evaluación de la residualidad de plaguicidas en papa (Solanum tuberosum) cultivada en Ventaquemada (Boyacá)

Simple item page
dc.contributor.advisorChaparro Acuña, Sandra Patriciaspa
dc.contributor.authorLara Sandoval, Adriana Elizabeth
dc.date.accessioned2019-05-10T22:12:17Z
dc.date.available2019-05-10T22:12:17Z
dc.date.issued2015
dc.description1 recurso en línea (105 páginas) : figuras, tablas.spa
dc.description.abstractElectrochemical methods for of glyphosate, paraquat, methomyl, carbofuran and mancozeb determination were validated for quantification in potato. The study was conducted using a voltammetric analyzer as supporting electrolyte Britton-Robinson buffer solution, the working electrode of glassy carbon, Ag / AgCl as reference electrode and platinum as counter electrode. Pesticides were extracted by solid-liquid partition method. Validation was carried out by two analysts who evaluated six batches consisting of two natural samples, two standard and two spiked or fortified samples. The methods showed no significant difference generating accurate and reliable results for the quantification of pesticides in samples of potato with a precision (%) and accuracy (%) of: 86.23 and 94.11 glyphosate, paraquat 86,04 and 96, 90, 85.93 and 83.016 methomyl, carbofuran 88.63 and 95.56 and 87.65 and 88.39 mancozeb, with a confidence level of 95%. The detection and quantification limits for the compounds were: 0.074 ppm and 0.19 ppm for glyphosate, 0.05 ppm and 0.55 ppm for paraquat, 0.12 ppm and 0.32 ppm for methomyl, 0.5 ppm and 1.98 ppm for carbofuran and 0.015 ppm and 0.076 ppm for mancozeb. Control charts were developed to evaluate the performance of validated methods and no value exceeded the warning limits. 100 samples collected in Ventaquemada village (Boyacá) were evaluated and the results state that none of the samples exceeded the maximum residue limit (MRL) of glyphosate (15 mg / kg) and mancozeb (0.2 mg / kg), 97 paraquat exceeded the MRL (0.05 mg / kg), 100 exceeded the MRL carbofuran (0.2 mg / kg) and methomyl not detected in any of the samples. In conclusion, paraquat herbicide and insecticide carbofuran are commonly used in this village to control weeds and insects, like the fungicide mancozeb, which is not used so indiscriminately as the previous two.eng
dc.description.abstractLos métodos electroquímicos para la determinación de glifosato, paraquat, metomil, carbofurano y mancozeb fueron validados para su cuantificación en papa. El estudio fue llevado a cabo en un analizador voltamperométrico usando como electrolito de soporte solución buffer Britton-Robinson, electrodo de trabajo de carbón vítreo, Ag/AgCl como electrodo de referencia y platino como electrodo auxiliar. Los plaguicidas en papa fueron extraídos por reparto sólido-líquido. La validación fue llevada a cabo por dos analistas quienes evaluaron seis lotes compuestos por dos muestras naturales, dos estándares y dos muestras adicionadas o fortificadas. Los métodos no presentaron diferencia significativa generando resultados precisos y confiables para la cuantificación de los plaguicidas en muestras de papa con una precisión (%) y exactitud (%) de: glifosato 86,23 y 94,11, paraquat 86,04 y 96,90, metomil 85,93 y 83,016, carbofurano 88,63 y 95,56 y mancozeb 87,65 y 88,39, con un nivel de confiabilidad del 95%. Los límites de detección y cuantificación para los compuestos fueron: 0,074 ppm y 0,19 ppm para glifosato, 0,05 ppm y 0,55 ppm para paraquat, 0,12 ppm y 0,32 ppm para metomil, 0,5 ppm y 1,98 ppm para carbofurano y 0,015 ppm y 0,076 ppm para mancozeb. Se elaboraron cartas control para evaluar el desempeño de los métodos validados y ningún valor sobrepasó los límites de advertencia. Se evaluaron 100 muestras recolectadas en el municipio de Ventaquemada (Boyacá) y los resultados exponen que ninguna de las muestras excedieron el Límite Máximo Residual (LMR) de glifosato (15 mg/kg) y mancozeb (0,2 mg/kg), 97 sobrepasaron el LMR de paraquat (0,05 mg/kg), 100 excedieron el LMR de carbofurano (0,2 mg/kg) y no se detectó metomil en ninguna de las muestras. En conclusión, el herbicida paraquat y el insecticida carbofurano son los plaguicidas más usados en este municipio para el control de malezas e insectos, al igual que el fungicida mancozeb, el cual no se usa tan indiscriminadamente como los dos anteriores.spa
dc.description.degreelevelMaestríaspa
dc.description.degreenameMagíster en Químicaspa
dc.description.notesBibliografía y webgrafía : páginas 67-81.spa
dc.format.mimetypeapplication/pdfspa
dc.identifier.citationLara Sandoval, A. E. (2015). Evaluación de la residualidad de plaguicidas en papa (Solanum tuberosum) cultivada en Ventaquemada (Boyacá). (Tesis de Maestría). Universidad Pedagógica y Tecnológica de Colombia, Tunja. http://repositorio.uptc.edu.co/handle/001/2586spa
dc.identifier.urihttp://repositorio.uptc.edu.co/handle/001/2586
dc.language.isospaspa
dc.publisherUniversidad Pedagógica y Tecnológica de Colombiaspa
dc.publisher.facultyFacultad de Ciencias. Escuela de Posgrados. Maestría en Químicaspa
dc.relation.referencesM. R. Jan, J. Shah, M. Muhammad, and B. Ara, "Glyphosate herbicide residue determination in samples of environmental importance using spectrophotometric method," Journal of Hazardous Materials, vol. 169, pp. 742-745, 9/30/ 2009.spa
dc.relation.referencesI. K. Dimitrakopoulos, N. S. Thomaidis, N. C. Megoulas, and M. A. Koupparis, "Effect of suppressor current intensity on the determination of glyphosate and aminomethylphosphonic acid by suppressed conductivity ion chromatography," Journal of Chromatography A, vol. 1217, pp. 3619-3627, 5/28/ 2010spa
dc.relation.referencesMunicipio de Ventaquemada. Esquema de ordenamiento territorial sistema económico. [online]. Disponible el 7 de Febrero del 2015 en http://cdim.esap.edu.co/BancoMedios/Documentos%20PDF/economico%20-%20ventaquemada%20(67%20pag%20-%20516%20kb).pdfspa
dc.relation.referencesG. J. Scott, "Tendencias cruzadas: El consumo y utilización de la papa en América Latina entre 1961 y 2007 y sus implicancias para la industria " Revista latinoamericana de la papa, vol. 16, pp. 1-38, 2011.spa
dc.relation.referencesL. G. Arismendi, "Investigación sobre el cultivo de la papa (Solanum tuberosum L.) en el Oriente de Venezuela," Revista UDO Agrícola, vol. 2, pp. 1-7, 2002.spa
dc.relation.referencesM. Larsbo, J. Stenström, A. Etana, E. Börjesson, and N. J. Jarvis, "Herbicide sorption, degradation, and leaching in three Swedish soils under long-term conventional and reduced tillage," Soil and Tillage Research, vol. 105, pp. 200-208, 11// 2009.spa
dc.relation.referencesMinisterio de Salud. Salud Pública, Calidad e Inocuidad de Alimentos 2013. [online]. Disponible en: http://www.minsalud.gov.co/salud/Documents/general-temp-jd/SISTEMA%20DE%20MEDIDAS%20SANITARIAS%20Y%20FITOSANITARIAS%20-%20MSF.pdf [Consulta: 6 de enero de 2014]spa
dc.relation.referencesM. R. Jan, J. Shah, and H. Khan, "Investigation of new indirect spectrophotometric method for the determination of carbofuran in carbamate pesticides," Chemosphere”, vol. 52, pp. 1623-1626, 9// 2003.spa
dc.relation.referencesFAO. Código Internacional de conducta para la Distribución y utilización de Plaguicidas. Versión Revisada. FAO. Roma. pp. 7. 2006.spa
dc.relation.referencesInstituto Colombiano Agropecuario ICA. Manejo Fitosanitario del Cultivo de la papa. Medidas para la temporada invernal. Produmedios. pp. 5. 2011spa
dc.relation.referencesP. Castro, J. Ramos. Determinación de residuos de plaguicidas organofosforados en muestras de tomate de la ciudad de Bogotá 2005. (Universidad de los Andes, Bogotá, Colombia), [online]. Disponible en: http://www.guaica.uniandes.edu.co:5050/dspace/bit stream/1992/661/1/mi_1106.pdf.spa
dc.relation.referencesEPA, 2001. The Determination of whether dithiocarbamate pesticides share a common mechanism of toxicity. Health effects Division, Office of Pesticide Programs, Washingtonspa
dc.relation.referencesS. I. Pereira,; P. I. Figueiredo,; A. S.; Barros, M.C. Dias, C. Santos, Duarte, L. F.; Gil, A. M. “Changes in the metabolome of lettuce leaves due to exposure to mancozeb pesticide”. Food Chemistry Vol. 154 pp. 291–298. 2014spa
dc.relation.referencesC., Colosio. “Ethylenethiourea in urine as an indicator of exposure to mancozeb in vineyard workers” .Toxicology letters. Vol. 134 pp. 133-40. 2002spa
dc.relation.referencesE.D.; Caldas, M.H.; Conceicao, M.C.C. Miranda, L.R de Souza.;.” Determination of dithiocarbamate fungicide residues in food by a spectrophotometric method using a vertical disulfide reaction system.” J. Agric. Food Chem. Vol. 49 pp. 4521- 4525. 2001spa
dc.relation.referencesS. Sonia, L. Marcelo Herbicides. “Theory and Applications. Published by InTechJanezaTrdine” Rijeka, Croatia. pp. 265. 2011.spa
dc.relation.referencesI. Armenta, S.; Garrigues, S.; De la guardia, M. “Solid sampling Fourier transform infrared determination of Mancozeb in pesticide formulations”. Talanta. Vol. 65(4) pp. 971-979. 2005.spa
dc.relation.referencesC.; BLASCO, G. FONT,; Y. PICÓ. “Determination of dithiocarbamates and metabolites in plants by liquid chromatography–mass spectrometry”. J. Chromatogr. A. Vol. 1028 pp. 267-276. 2004.spa
dc.relation.referencesJ. Moros,; S.; Armenta, S.; Garrigues, M. Guardia.”Comparison of two vibrational procedures for the direct determination of mancozeb in agrochemicals.” Talanta Vol. 72 pp. 72–79. 2007.spa
dc.relation.referencesNorma ISO 8402-1995. Gestión de la calidad y aseguramiento de la calidad. Vocabulario.spa
dc.relation.referencesEurachem. Métodos analíticos adecuados a su propósito. Segunda Edición. México pag 7-14. 2005.spa
dc.relation.referencesJM. Green. “A Practical Guide to Analytical Method Validation.” Analytical Chemistry, Vol. 68. pp. 305- 309. 1996spa
dc.relation.referencesE. T. Soler. "Validation of Qualitative Analytical Methods " Doctorate Doctoral thesis Department of Analytical Chemistry and Organic Chemistry, Universitat Rovira I Virgili, Tarragona, 2006.spa
dc.relation.referencesMetAs & Metrólogos Asociados. “Cartas de control para instrumentos de medición.” La Guía MetAs, Vol. 6 pp. 1 – 5. 2004.spa
dc.relation.referencesV., Feigenbaum Armand. Control de calidad total.3ra Edición-CESCA. 1994.spa
dc.relation.referencesW. E. Basil H. Vasssos, "Electroquimica Analitica," in Electronallytical Chemistry vol. 121, Limusa, Ed., 1987, pp. 1-303.spa
dc.relation.referencesR. F. Teófilo, Efraim L. Rris, Gilmare A. da Silva, José F. Paiva and Lauro T. Kubota. “Glyphosate Determination in Soil, Water and Vegetables Using DPV Optimized by Response Surface Methodology” Portugaliae Electrochimica Acta Vol. 26/4 p. 325-337, 2008.spa
dc.relation.referencesM. A. E. Mhammedi, M. Bakasse, and A. Chtaini, "Electrochemical studies and square wave voltammetry of paraquat at natural phosphate modified carbon paste electrode," Journal of Hazardous Materials, vol. 145, pp. 1-7, 6/25/ 2007.spa
dc.relation.referencesY. Ni, P. Qiu, S. Kokotc, "Simultaneous voltammetric determination of four carbamate pesticides with the use of chemometrics," Anal Chim Acta, vol. 537 (1), pp. 321-330, 2005spa
dc.relation.referencesP. Qiu,; y Y. Nian. “ Determination of ziram in vegetable samples by square wave voltammetry”. Chinese Chem. Lett. Vol. 19 pp. 1337–1340. 2008.spa
dc.relation.referencesV.; Leoni, A. M. Caricchia,; y S. Chiavarini. “Multiresidue method for quantitation of organophosphorous pesticides in vegetable and animal foods”. J. AOAC. Int. Vol. 75: pp. 511-518. 1992.spa
dc.relation.referencesICONTEC: NTC 2322. “Vidrio. Material de vidrio para laboratorio. Balones volumétricos de un solo trazo”. 1987.spa
dc.relation.referencesE. V. Sierra; M. A. Méndez; V. M. Sarria; M. T. Cortés. “Electrooxidación de glifosato sobre electrodos de níquel y cobre”. Quím. Núm. vol.31 no.2 pp.220-226. São Paulo. 2008.spa
dc.relation.referencesV. Stara, M. Kopanica, Coll. Czech. Chem. Comm. “Some remarks concerning polarographic determination of sulphur-containing herbicides.” Collection of Czechoslovak Chemical. Communications. vol. 49, pp. 1282-1288. 1984.spa
dc.relation.referencesM. Subbalakshmamma, M. Sreedhar, N. V. Jyothi, J. Damodar, S. J. Reddy, Trans. “Electrochemical determination of methomyl” Saest Vol. 131 pp. 34 35 1999spa
dc.relation.referencesF. Mogyorody “Reaction pathways in the electrochemical degradation of thiocarbamate herbicides in NaCl solution”. Journal of Applied Electrochemistry Vol. 36. pp. 635-642. 2006.spa
dc.relation.referencesM. Shan Lin, B. Iuan Jan, Hoang-Jyh Leu, Jhy Shing Lin.. “Trace measurement of dithiocarbamate based pesticide by adsorptive stripping voltammetry.” Analytica Chimica Acta Vol. 388 pp. 111-117. 1999.spa
dc.relation.referencesC. Swarupa, M. Siva Prasad M. Dhananjayulu y N.Y. Sreedhar. “Electrochemical determination and reduction behaviour of mancozeb at glassy carbon electrode modified with polyaniline based nanosensors.” International Journal of Scientific & Engineering Research, Vol. 4, Issue 7, July- 2013spa
dc.relation.referencesL. Besagarahally, Bhaskara, Padmarajaiah N. Direct SensitiveSpectrophotometric Determination of Glyphosate by Using Ninhydrin as a Chromogenic Reagent in Formulations and Environmental Water Samples. Helvetica Chimia Acta, Vol. 89, Issue 11, pp. 2686-2693. Nov-2006.spa
dc.relation.referencesAOAC. Association of official analytical chemists. Official methods of analysis agricultural chemicals contaminants. Paraquat in pesticide fomulations, spectrophotometric Method. 227-228. 1990.spa
dc.relation.referencesM, Kaur M., Ashok B. Singh. “Fourth Derivative Spectrophotometric Method for the Determination of Fungicide Maneb Using Sodium Molybdate”. American Journal of Analytical Chemistry, Vol. 2 pp. 158-163. 2011.spa
dc.relation.referencesJ. A. Ramírez y M. Lacasaña. "Plaguicidas: clasificación, uso, toxicología y medición de la exposición," Arch Prev Riesgos Labo, vol. 4, pp. 67-75, 2001spa
dc.relation.referencesA. Guiberteau, T. G. Díaz, F. Salinas, and J. M. Ortiz, "Indirect voltammetric determination of carbaryl and carbofuran using partial least squares calibration," Analytica Chimica Acta, vol. 305, pp. 219-226, 4/20/ 1995.spa
dc.relation.referencesNorma NCR 233:1994 Plaguicidas Valores Suspensibilidad Formulaciones (Valores Mínimos Permitidos para la Suspensibilidad del Ingrediente Activo en Formulaciones de Plaguicidas), L. G. N°178, Ed., ed, 1998, pp. 1-6.spa
dc.relation.referencesC. Hao, D. Morse, F. Morra, X. Zhao, P. Yang, and B. Nunn, "Direct aqueous determination of glyphosate and related compounds by liquid chromatography/tandem mass spectrometry using reversed-phase and weak anion-exchange mixed-mode column," Journal of Chromatography A, vol. 1218, pp. 5638-5643, 8/19/ 2011.spa
dc.relation.referencesG.M., Williams, R., Kroes, I.C., Munro. Safety evaluation and risk assessment of the herbicide Roundup and its active ingredient, glyphosate, for humans. Regulatory Toxicology and Pharmacology 31, 117–165. 2000.spa
dc.relation.referencesJ.E. Franz, M.K. Mao, J.A. Sicorski, “Glyphosate: A Unique Global Herbicide, Monograph 189”, American Chemical Society, Washington, DC, pp 653. 1997.spa
dc.relation.referencesR.J. Vreeken, P., Speksnijder, I., Bobeldijk-Pastorova, Noij, Th.H.M. “Selective analysis of the herbicides glyphosate and aminomethylphosphonic acid in water by online solid-phase extraction-high-performance liquid chromatography-electrospray ionization mass spectrometry”. Journal of Chromatography. Vol 794, pp. 187–199. 1998.spa
dc.relation.referencesE., Dallegrave, F., DiGiorgioMantese, R., Soares Coelho, J., Drawans Pereira, Dalsenter, P.R., Langeloh, A. “The teratogenic potential of the herbicide glyphosate-Roundup in Wistar rats”. Toxicology Letters Vol. 142, pp. 45–52. 2003.spa
dc.relation.referencesC. Gasnier, C., Dumont, N., Benachour, E., Clair Chagnon, M.-C., Séralini, G.-E. “Glyphosate-based herbicides are toxic and endocrine disruptors in human cell lines”. Science Direct Toxicology Vol. 262, pp. 184–191. 2009.spa
dc.relation.referencesLe D.G., Couteur, A.J., McLean, M.C., Taylor, B.L. Woodham, R.G., Board, “Pesticides and Parkinson's disease”. Biomedicine & Pharmacotherapy Vol. 53, pp. 122–130. 1999.spa
dc.relation.referencesS., Richard, S., Moslemi, H., Sipahutar, N. Benachour, y G.E. Seralini, “ Differential effects of glyphosate and Roundup on human placental cells and aromatase”. Environmental Health Environmental Health Perspectives. Vol. 113 pp. 716-20. 2005.spa
dc.relation.referencesB. Cartigny, N. Azaroual, M. Imbenotte, D. Mathieu, E. Parmentier, G. Vermeersch, et al., "Quantitative determination of glyphosate in human serum by 1H NMR spectroscopy," Talanta, vol. 74, pp. 1075-1078, 1/15/ 2008.spa
dc.relation.referencesC.V. Waiman, M. J. Avena, M. Garrido; B. Fernández,; G Zanini. “A simple and rapid spectrophotometric method to quantify the herbicide glyphosate in aqueous media. Application to adsorption isotherms on soils and goethite”. Geoderma, Vol. 170, pp. 154-158. 2012.spa
dc.relation.referencesY. S. Hu., Y. Q. Zhao. “Removal of glyphosate from aqueous environment by adsorption using water industrial residual”. Desalination, Vol. 271. pp. 150-156. 2011.spa
dc.relation.referencesM. Rasul Jan J. Shah. “Glyphosate herbicide residue determination in samples of environmental importance using spectrophotometric method” Journal of Hazardous materials, Vol. 169. pp. 742-745. 2009spa
dc.relation.referencesI. L. Petersen G. Tomasi H. Sorensen “The use of environmental metabolomics to determine glyphosate level of exposure in rapeseed (Brassica napus L.) seedlings”. Environmental Pollution, Vol. 159. pp. 3071-3077. 2011spa
dc.relation.referencesH. Lan, Z. Jiao, W. He, A. Wang, H. Liu, J. Qu. “Removal of Glyphosate from Water by Electrochemically Assisted MnO2 Oxidation Process”. Separation and Purification Technology. Vol. 117. pp 30-34. 2013.spa
dc.relation.referencesM. Chen, Z. Yun Cao, Z. Wei Zhu. “Direct determination of glyphosate and its major metabolite, aminomethylphosphonic acid, in fruits and vegetables by mixed-mode hydrophilic interaction/weak anion-exchange liquid chromatography coupled with electrospray tandem mass spectrometry”. Journal of Cromatography A, Vol. 1272. pp. 90-99. 2013.spa
dc.relation.referencesH., Kataoka, S., Ryu, N., Sakiyama, M., Makita, “Simple and rapid determination of the herbicides glyphosate and glufosinate in river water, soil and carrot samples by gas chromatography with flame photometric detection”. Journal of Chromatography A Vol. 726, pp. 253–258. 1996.spa
dc.relation.referencesS.-H. Tseng, Y.-W. Lo, P.-C. Chang, S.-S. Chou, H.-M., Chang. “Simultaneous quantification of glyphosate, glufosinate, and their major metabolites in rice and soybean sprouts by gas chromatography with pulsed flame photometric detector”. Journal of Agricultural and Food Chemistry Vol. 52 pp. 4057–4063. 2004.spa
dc.relation.referencesN. Laguarda, F. Werner, E. García, J. Ibañes, L. Gil. “Glyphosate detection by voltammetric techniques. A comparison between statistical methods and an artificial neural network”. Sensors and Actuators B Vol. 171. pp. 528-536. 2012.spa
dc.relation.referencesE. Songa, O. Arotiba, J. Owino, N. Jahed. “Electrochemical detection of glyphosate herbicide using horseradish peroxidase immobilized on sulfonated polymer matrix”. Bioelectrochemistry, Vol. 75. pp. 117-123. 2009.spa
dc.relation.referencesS. Kodama, Y. Ito, A., Taga, Y. Nomura, A. Yamamoto, S. Chinaka, K., Suzuki, Yamashita, T., Kemmei, T., Hayakawa. “A fast and simple analysis of glyphosate in tea beverages by capillary electrophoresis with on-line copper(II)-Glyphosate complex formation”. Journal of Health Science Vol. 54. pp. 602–606. 2008.spa
dc.relation.referencesF., Sánchez-Bayo, R.V., Hyne, K.L., Desseille. “An amperometric method for the detection of amitrole, glyphosate and its aminomethyl-phosphonic acid metabolite in environmental waters using passive samplers”. Analytica Chimica Acta. Vol. 675. pp. 125–131. 2010.spa
dc.relation.referencesJ. Jiang y C. Lucy. “Determination of glyphosate using off-line ion exchange preconcentration and capillary electrophoresis-laser induced fluorescence detection.” Talanta, Vol. 72. pp. 113-118. 2007.spa
dc.relation.referencesM. Ibañez, O. Pozo, J. Sancho, F. López, F. Hernández “Re-evaluation of glyphosate determination in water by liquid chromatography coupled to electrospray tandem mass spectrometry.” Journal of Cromatography A, Vol. 1134. pp. 51-55. 2006.spa
dc.relation.referencesM. Kim, J. Stripeikis, F. Iñón, and M. Tudino, "A simplified approach to the determination of N-nitroso glyphosate in technical glyphosate using HPLC with post-derivatization and colorimetric detection," Talanta, vol. 72, pp. 1054-1058, 5/15/ 2007.spa
dc.relation.referencesR.H. Bromilow. “Paraquat and sustainable agriculture”. Pest Management. Science. Vol. 60 pp. 340- 349. 2004spa
dc.relation.referencesEl Harmoudi, H. Achak, M. Farahi, A. Lahrich, S. El Gaini, L. Abdennouri, M. Bouzidi, A. Bakasse, M. El Mhammedi, M.A. “Sensitive determination of paraquat by square wave anodic stripping voltammetry with chitin modified carbon paste electrode”. Talanta: Vol. 115 pp. 172-177. 2013.spa
dc.relation.referencesCodex Alimentarius. 2015. Residuos de plaguicidas en alimentos y piensos. [online]. Disponible en http://www.codexalimentarius.net/pestres/data/pesticides/details.html?id=57spa
dc.relation.referencesRíos, J. 2012. Paraquat. [online]. Disponible en http://escuela.med.puc.cl/publ/guiaintoxicaciones/Paraquat.html dd-mm-aa?spa
dc.relation.referencesM.E. Rozas. Convenio de Rotterdam sobre información y consentimiento previo. Red de acción en plaguicidas y sus alternativas para América Latina. [online]. Disponible en: http://www.rap-al.org/index.php?seccion=4&f=convenio_rotterdam.phpspa
dc.relation.referencesAgencia de Protección Ambiental de los Estados Unidos. 1997. [online]. Disponible en http://www.epa.gov/oppsrrd1/REDs/factsheets/0262fact.pdfspa
dc.relation.referencesP. Paixão, P. Costa, T. Bugalho, C. Fidalgo, and L. M. Pereira, "Simple method for determination of paraquat in plasma and serum of human patients by high-performance liquid chromatography," Journal of Chromatography B, vol. 775, pp. 109-113, 7/25/ 2002.spa
dc.relation.referencesM.K.; Rai, J.V. Das; y , V.K. Gupta. “A sensitive determination of paraquat by spectrophotometry”. Talanta. Vol. 45(2) pp. 343-348. 1997.spa
dc.relation.referencesV. Y.; Taguchi, S. W.; Jenkins, P.W.; Crozier, y D.T. Wang, “Determination of diquat and paraquat in water by liquid chromatography (electrospray ionization) mass spectrometry”. J Am Soc Mass Spectrom. Vol. 8 pp. 830-839. 1998.spa
dc.relation.referencesB. Saad,; M.; Ariffin, y, M.I. “Saleh Flow injection potentiometric determination of paraquat in formulations and biological samples”. Talanta. Vol. 47(5) pp. 1231-1236. 1998.spa
dc.relation.referencesC. Masini, "Development of a sequential injection–square wave voltammetry method for determination of paraquat in water samples employing the hanging mercury drop electrode," Anal Bioanal Chem, vol. 393, pp. 1807-1903, 2010.spa
dc.relation.referencesI. Rühling,; H. Schäfer,; y W. Ternes. “HPLC online reductive scanning voltammetric detection of diquat, paraquat and difenzoquat with mercury electrodes”. Fresenius J. Anal. Chem. Vol. 364 pp. 565–569. 1999spa
dc.relation.referencesD. Souza,; y, S. Machado. “Electrochemical detection of the herbicide paraquat in natural water and citric fruit juices using microelectrodes”. Anal Chim. Acta. Vol 546 pp. 85–91. 2005.spa
dc.relation.referencesP.M. Monk S. C. Turner, y S.P. Akhtar. “Electrochemical behaviour of methyl viologen in a matrix of paper”. Electrochim. Acta. Vol. 44. pp. 4817 - 4826. 1999.spa
dc.relation.referencesB. O. Luciana, M. C. Carlos y C. Jorge, Masini. “Development of a sequential injection–square wave voltammetry method for determination of paraquat in water samples employing the hanging mercury drop electrode.” Anal Bioanal Chem. Vol. 396 pp. 1897–1903. 2010.spa
dc.relation.referencesM. A. E. Mhammedi, M. Bakasse, and A. Chtaini, "Electrochemical studies and square wave voltammetry of paraquat at natural phosphate modified carbon paste electrode," Journal of Hazardous Materials, vol. 145, pp. 1-7, 6/25/ 2007.spa
dc.relation.referencesE; Zapp. ,D. Brondani; Vieira, I. C.; Scheeren, C. W.;, Dupont, J.; Barbosa, A. M.J., Ferreira V. S. Biomonitoring of methomyl pesticide by laccase inhibition on sensor containingplatinum nanoparticles in ionic liquid phase supported in montmorillonite”. Sensor Actuator B. Vol. 155 pp. 331–339. 2011spa
dc.relation.referencesF.K.; Mohammad, A.S. Alias; G.A.M. Faris,; Baggaou, B.K.H. “Application of an electrometric method for measurement of blood cholinesterase activity in sheeps, goats and cattle treated with organophosphate dyes”, J. Vet. Med. 54: 140. 2007.spa
dc.relation.referencesM. L. A. I. Andjelka V. Tomašević, Slobodan D. Petrović,, Mića B. Jovanović Y Dušan Ž. Mijin, "A study of the electrochemical behaviour of methomyl on a gold electrode in a neutral electrolyte," Journal of the Serbian Chemical Society, vol. 74, pp. 573-579, 2009.spa
dc.relation.referencesOMS. 2010. The WHO Recommended Classification of Pesticides by Hazard and Guidelines to Classification. WHO Press Ed. Switzerland. 22.spa
dc.relation.referencesMinistry of environment. Government of Japan. 2015. Strategic Programs on Environmental Endocrine Disruptors ´98. SPEED ’98. Disponible en internet desde: http://www.env.go.jp/en/chemi/ed/speed98/sp98t3.html. 10/12/2014spa
dc.relation.referencesGuanggang, X.; Diqiu, L.; Jianzhong, Y.; Jingmin, G.; Huifeng, Z.; Mingan, S., Liming, T. “Carbamate insecticide methomyl confers cytotoxicity through DNA damage induction”. Food Chem Toxicol. Vol. 53 pp. 352–358. 2013.spa
dc.relation.referencesM.J. Ellenhorn. “Diagnosis and Treatment of Human Poisoning, 2nd ed., Williams & Wilkins, Baltimore”, Medical Toxicology pp. 1623–1625. 1997.spa
dc.relation.referencesG. P. Yang,; Y. H. Zhao,; X. L. Lu,, X. C. Gao, “Adsorption of methomyl on marine sediments”. Colloid Surfaces A. Vol. 264 pp. 179–186. 2005.spa
dc.relation.referencesA. Tomašević, E. Kiss, S. Petrović, and D. Mijin, "Study on the photocatalytic degradation of insecticide methomyl in water," Desalination, vol. 262, pp. 228-234, 11/15/ 2010.spa
dc.relation.referencesF., Moriya, Y. Hashimoto.“A fatal poisoning caused by methomyl and nicotine.” Forensic Sci Int. Vol. 149 pp. 167–170. 2005.spa
dc.relation.referencesR. S. Juang, C. H. Chen. “Comparative study on photocatalytic degradation of methomyl and parathion over UV-irradiated TiO2 particles in aqueous solutions”. J Tai I Chem Eng. Vol. 45 pp. 989–995. 2014.spa
dc.relation.referencesA.; Bermúdez, D.; Fernández, M.; Pateiro, J.C.; Novoa, J.; Simal, Arias, M. “Adsorption and desorption kinetics of carbofuran in acid soils. J”. Hazard Mater. Vol. 190 pp. 159-167. 2011.spa
dc.relation.referencesU. Tamrakar, A.K Pillai, V. Gupta,. “A Simple Colorimetric Method for the Determination of Carbofuran and its application in Environmental and Biological Samples.” J. Braz. Chem. Soc.Vol. 18 (2) pp. 337-341. 2007.spa
dc.relation.referencesO. Bhargavi, K. Kiran, K. Suvardhan, D. Rekha, K. Janardhanam, and P. Chiranjeevi, "A Sensitive Determination of Carbofuran by Spectrophotometer using 4, 4-azo-bis-3, 3′5, 5′-tetra bromoaniline in various Environmental Samples," E-Journal of Chemistry, vol. 3, pp. 68-77, 2006.spa
dc.relation.referencesN. Gera,; N.; Kiran, A. Mahmood. Carbofuran administration induces genotoxic effects in epithelial cells across crypt–villus axis in rat intestine.” Pestic Biochem Phys. Vol. 100 pp. 280-283. 2011spa
dc.relation.referencesB. Sharma; K. Gopal. “Changes in lactic acid content and activity of lactate dehydrogenase in clarias batrachus, exposed to carbaryl.” Toxicological & Environmental Chemistry. Vol. 47. pp. 89,-95. 1995.spa
dc.relation.referencesS. M Cohen; M.; Cano, L. S.; Johnson; ST. M. K.; John, M.; Asmoto, E.M.; Garland, J.H. Thyssen,; G. K.; sangha, Van Goethem, D.L. “Mitogenic effects of propoxur on male rat bladder urothelium Carcinogenesis.” Vol.15 (11): pp. 2593-2597. 1994.spa
dc.relation.referencesP.O., Otieno J.O. Lalah, M., Virani, I.O. Jondiko K.W. Schramm, “Carbofuran and its toxic metabolites provide forensic evidence for furadan exposure in vultures (Gyps africanus) in Kenya, Bull”. Environ. Contam. Toxicol. Vol. 84 (5) pp. 536–544. 2010.spa
dc.relation.referencesS. Tennakoon, B. Perera, L. Haturusinghe, “Intentional poisoning cases of animals with anticholinesterase pesticide-carbofuran in Sri Lanka”. Legal Med. Vol 11 pp. 500–502. 2009.spa
dc.relation.referencesE. P., Syrago-Styliani, G., Evagelos, T., Anthony, A. S. Panayotis. “Gas chromato- graphic-tandem mass spectrometric method for the quantitation of carbofuran, carbaryl and their main metabolites in applicators’ urine”. J Chromatog A, Vol. 1108 pp. 99-110. 2006.spa
dc.relation.referencesN. L. Pacioni, A. V. Veglia, “Determination of carbaryl and carbofuran in fruits and tap water by cyclodextrin enhanced fluorimetric method”. Anal Chim Acta. Vol. 488 pp. 193-202. 2003.spa
dc.relation.referencesX. Sun,; Y. Zhu, X. Wang. Amperometric immunosensor based on deposited gold nanocrystals/4,40-thiobisbenzenethiol for determination of carbofuran.” Food Control Vol. 28 pp. 184-191. 2012.spa
dc.relation.referencesR., Bravo L.M.; Caltabiano, C.; Fernandez, K.D.; Smith, M.; Gallegos, R.D.; Whitehead, J.R.; Weerasekara., Restrepo, P., Bishop, A.M., Pérez, J.J., Needham, L.L., Barr, D.B. “Quantification of phenolic metabolites of environmental chemicals in human urine using gas chromatography–tandem mass spectrometry and isotope dilution quantification” J. Chromatogr. B Analyt Technol Biomed Life Sci. Vol. 820(2) pp. 229-236. 2005spa
dc.relation.referencesR., Paro, G. M., Tiboni, R., Buccione, G., Rossi, V., Cellini, R., Canipari. “The fungicide mancozeb induces toxic effects on mammalian granulosa cells.” Toxicology and Applied Pharmacology, Vol. 260, pp. 155–161. 2012spa
dc.relation.referencesA. Easton, K., Guven, D. I. Pomerai. “Toxicity of the dithiocarbamate fungicide mancozeb to the nontarget soil nematode, Caenorhabditis elegans.” Journal of Biochemical and Molecular Toxicology, Vol. 15 pp. 15–25. 2001.spa
dc.relation.referencesM.A. Dominguez, G. Peñuela y M. A. Flórez. “Método analítico para la determinación de etilentiourea (ETU) subproducto del mancozeb en un Andisol del Oriente Antioqueño”. Rev. Fac. Ing. Univ. Antioquia, Vol.49. pp. 42-49. 2009.spa
dc.rightsCopyright (c) 2015 Universidad Pedagógica y Tecnológica de Colombiaspa
dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.rights.coarhttp://purl.org/coar/access_right/c_abf2spa
dc.rights.creativecommonsAtribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)spa
dc.rights.urihttps://creativecommons.org/licenses/by-nc/4.0/spa
dc.subject.armarcResiduos de plaguicidas - Estudio de casos
dc.subject.armarcPersistencia de los plaguicidas
dc.subject.armarcMaestría en Química - Tesis y disertaciones académicas
dc.subject.armarcAgrosaviaspa
dc.titleEvaluación de la residualidad de plaguicidas en papa (Solanum tuberosum) cultivada en Ventaquemada (Boyacá)spa
dc.typeTrabajo de grado - Maestríaspa
dc.type.coarhttp://purl.org/coar/resource_type/c_bdccspa
dc.type.coarversionhttp://purl.org/coar/version/c_970fb48d4fbd8a85spa
dc.type.contentTextspa
dc.type.driverinfo:eu-repo/semantics/masterThesisspa
dc.type.redcolhttps://purl.org/redcol/resource_type/TMspa
dc.type.versioninfo:eu-repo/semantics/publishedVersionspa
Files
Original bundle
Now showing 1 - 2 of 2
Thumbnail Image
Name:
TGT_1206.pdf
Size:
1.66 MB
Format:
Adobe Portable Document Format
Description:
Archivo principal
Descargar
Thumbnail Image
Name:
A_AELS.pdf
Size:
644.73 KB
Format:
Adobe Portable Document Format
Description:
Autorización publicación
Descargar
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
14.45 KB
Format:
Item-specific license agreed upon to submission
Description:
Descargar
Collections
AHG. Trabajos de Grado y Tesis